catena-Poly[copper(II)-bis(μ-2-formyl-6-methoxyphenolato-κ4 O 2,O 1:O 1,O 6)-[(methanol-κO)sodium]-μ-perchlorato-κ2 O:O′]
نویسندگان
چکیده
In the title heterodinuclear complex, [CuNa(C(8)H(7)O(3))(2)(ClO(4))(CH(3)OH)](n), the Cu(II) ion is five-coordinated by four O atoms from two 2-formyl-6-meth-oxy-phenolate anions and one O atom from a perchlorate anion in a distorted square-pyramidal geometry. The Na(+) ion is six-coordinated by four O atoms from two 2-formyl-6-meth-oxy-phenolate ligands, one O atom of a methanol mol-ecule and one O atom of a perchlorate anion. The perchlorate anions link the Na(+) and Cu(II) ions, forming a chain along [010]. O-H⋯O hydrogen bonds connect the chains. π-π inter-actions are present between the benzene rings [centroid-centroid distances = 3.566 (2) and 3.702 (2) Å]. The O atoms of the perchlorate anion are disordered over two sets of sites, with an occupancy ratio of 0.481 (8):0.519 (8).
منابع مشابه
catena-Poly[[[(dimethylmalonato-κ2 O:O′)(perchlorato-κO)copper(II)]-μ-bis(3-pyridylmethyl)piperazinediium-κ2 N 1′:N 4′] perchlorate dihydrate]
In the title compound, {[Cu(C(5)H(6)O(4))(ClO(4))(C(16)H(22)N(4))]ClO(4)·2H(2)O}(n), square-pyramidally coordinated Cu atoms with perchlorate and dimethyl-malonate ligands are connected into cationic sinusoidal coordination polymer chains by doubly protonated bis-(3-pyridylmeth-yl)piperazine (3-bpmp) ligands. The chains aggregate into pseudo-layers parallel to the (101) crystal planes by N-H⋯O ...
متن کاملcatena-Poly[[bis(μ-2-formyl-6-methoxyphenolato-1:2κ4 O 1,O 6:O 1,O 2)copper(II)sodium]-μ-tetrafluoridoborate-1:1′κ2 F:F′]
In the title heterodinuclear complex, [CuNa(BF(4))(C(8)H(7)O(3))(2)](n), the Cu(II) ion is four-coordinated by four O atoms of two 2-formyl-6-meth-oxy-phenolate ligands, giving rise to a square-planar geometry. The Na(+) ion is six-coordinated by four O atoms from the two ligands and two F atoms of two tetra-fluoridoborate anions. The tetra-fluoridoborate anion links the Na(+) ions, forming a o...
متن کاملcatena-Poly[[bis(μ-2-formyl-6-methoxyphenolato)copper(II)sodium]-μ-nitrato]
In the title heterodinuclear complex, [CuNa(C(8)H(7)O(3))(2)(NO(3))](n), the Cu(II) ion is five-coordinated in a square-pyramidal arrangement by four atoms of two different ligand molecules in equatorial positions and one remote nitrate O atom in the apical position. The Na(+) ion is eight-coordinated by four ligand O atoms and four nitrate O atoms. The ligand links the Cu(II) and Na ions, form...
متن کاملcatena-Poly[[bis(methanol-κO)bis(pyridine-κN)nickel(II)]-μ-tetrafluoroterephthalato-κ2 O:O′]
In the title compound, [Ni(C(8)F(4)O(4))(C(5)H(5)N)(2)(CH(4)O)(2)](n), the Ni(II) ion is located on an inversion center and is coordinated by four O atoms [Ni-O = 2.079 (4) Å] from two tetra-fluoro-terephthalate ligands and two methanol mol-ecules, and by two N atoms [Ni-N = 2.127 (4) Å] from two pyridine ligands in a distorted octa-hedral geometry. The Ni(II) ions are connected via the tetra-f...
متن کاملcatena-Poly[[(4-methylbenzoato-κO)manganese(II)]-μ-aqua-bis(μ-4-methylbenzoato-κ2 O:O′)[(4-methylbenzoato-κO)manganese(II)]-bis(μ-N,N-diethylnicotinamide)-κ2 N 3:O;O:N 3]
The asymmetric unit of the title complex, [Mn(2)(C(8)H(7)O(2))(4)(C(10)H(14)N(2)O)(2)(H(2)O)](n), contains two crystallographically independent units. In each one, the Mn(II) ions are bridged by two 4-methyl-benzoate (PMB) ligands and one water mol-ecule. In the crystal structure, each Mn(II) ion is coordinated by three PMB ligands, one water mol-ecule and two symmetry-related N,N-diethyl-nicot...
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عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012